Synthesis, Structure of Borylmagnesium, and Its Reaction with Benzaldehyde to Form Benzoylborane
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https://figshare.com/articles/dataset/Synthesis_Structure_of_Borylmagnesium_and_Its_Reaction_with_Benzaldehyde_to_Form_Benzoylborane/2992003
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资源简介：
The reaction of boryllithium 2 with 1.0 or 0.5 equiv of MgBr2·OEt2 provided boryl Grignard reagents, borylmagnesium bromides 3 and 4, or bis(boryl)magnesium 5. Structures of 3, 4, and 5 in the crystals and solutions indicated the ionic character of the B−Mg bonds. The reactivity of borylmagnesium 3 with benzaldehyde was different from that of boryllithium 2. Benzoylborane 7 was fully characterized as the first acylborane.
创建时间：
2016-02-28
