Rhodium Complexes of Cyclopropenylidene Carbene Ligands: Synthesis, Structure, and Hydroformylation Catalysis
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https://figshare.com/articles/dataset/Rhodium_Complexes_of_Cyclopropenylidene_Carbene_Ligands_Synthesis_Structure_and_Hydroformylation_Catalysis/2872834
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资源简介：
Rhodium(III) cyclopropenylidene complexes of the type [RhCl3(PPh3)2(2,3-di(aryl)cyclopropenylidene)] (Aryl = C6H5, 4-C6H4F) are synthesized via oxidative addition of 1,1-dichloro-2,3-diarylcyclopropene fragments to rhodium(I) precursors. The molecular structure of these complexes has been determined. Attempted hydroformylation of 1-hexene with these complexes leads to catalysis results which are strongly suggestive of decomposition of the carbene complex.
创建时间：
2016-02-26
