Tridecanuclear and Docosanuclear Manganese Phosphonate Clusters with Slow Magnetic Relaxation
收藏NIAID Data Ecosystem2026-03-06 收录
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Two novel mixed-valent manganese phosphonate clusters [MnIIMnIII12O6(OH)6(O3PC6H11)10(py)6] (1) and [MnII4MnIII18O12(O3PC6H11)8(O2CCH3)22(H2O)6(py)2] (2) are reported in this paper. Complex 1 is the first carboxylate-free manganese phosphonate cluster. While compound 2 appears to be the largest manganese cluster thus far that contains phosphonate ligand. Both show slow magnetic relaxation behaviors.
创建时间：
2016-07-05
