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Synthesis and Structure of Bis(diphenylphosphinimino)methanide and Bis(diphenylphosphinimino)methanediide Beryllium Complexes

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Synthesis_and_Structure_of_Bis_diphenylphosphinimino_methanide_and_Bis_diphenylphosphinimino_methanediide_Beryllium_Complexes/3473693
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资源简介:
Reactions of BeEt2 with bis­(diphenylphosphinimino)­methanes H2C­[PPh2NR]2 yielded the first bis­(diphenylphosphinimino)­methanide and bis­(diphenylphosphinimino)­methanediide beryllium complexes [CH­(PPh2N-2,6-i-Pr2C6H3)2]­BeEt (1), [C­(PPh2NSiMe3)2]­(BeEt)2 (2), and [C­(PPh2NPh)2]­(BeEt)2 (3), respectively. 1–3 were characterized by multinuclear NMR and IR spectroscopy as well as single-crystal X-ray diffraction.
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2016-07-19
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