Preparation and Diastereoselective <i>O</i><i>rtho</i>-Metalation of Chiral Ferrocenyl Imidazolines: Remarkable Influence of LDA as Metalation Additive
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The preparation of optically pure ferrocenyl imidazolines starting from ferrocenecarboxylic acid and the application to diastereoselective ortho-metalations is described highlighting the remarkable influence of lithium dialkylamides, especially LDA, as metalation additives (in combination with tert-butyllithium) on the diastereoselectivity.
创建时间：
2005-09-15
