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Spirobis(pentagerma[1.1.1]propellane): A Stable Tetraradicaloid

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Figshare2016-02-19 更新2026-04-29 收录
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In this contribution, we report a spirobis­(pentagerma[1.1.1]­propellane) derivative as a novel type of molecular architecture in cluster chemistry that features two spiro-fused [1.1.1]­propellane units and represents a stable tetraradicaloid species. The crucial issue of the nature of the interaction between the germanium bridgeheads was probed computationally, revealing weak bonding interactions between the formally unpaired electrons.

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2016-02-19
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