Transannular Reductive Rearrangement of α‑Amino Ketones: Construction of Aza-tricyclic Frameworks of Several Alkaloids
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https://figshare.com/articles/dataset/Transannular_Reductive_Rearrangement_of_Amino_Ketones_Construction_of_Aza_tricyclic_Frameworks_of_Several_Alkaloids/2403205
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资源简介:
Transannular
reductive rearrangement of bridged cyclic α-amino
ketones led to the aza-tricyclic frameworks azepinoindole, hydrolulolidine,
and hydrojulolidine of the typical alkaloids of Stemona, Aspidosperma, and Lycopodium,
respectively. This facile approach demonstrates the potential applicability
of the Clemmensen–Clemo–Prelog–Leonard reductive
rearrangement of tricyclic α-amino ketones for the aza-heterocycle
synthesis.
创建时间:
2016-02-19



