Ir3Co6 and Co3Fe3 Dithiolene Cluster Complexes: Multiple Metal–Metal Bond Formation and Correlation between Structure and Internuclear Electronic Communication
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π-Conjugated trinuclear iridium and cobalt dithiolenes undergo multiple metal–metal bond formation with Co2(CO)8 and Fe(CO)5, giving rise to Ir3Co6 nonanuclear and Co3Fe3 hexanuclear cluster complexes 5 and 6, respectively. 5 retains a planar framework and intense π conjugation across the three iridadithiolenes and the phenylene bridge, which results in intense electronic communication among the three Co2(CO)5 units in reduced mixed-valent states.
创建时间：
2016-02-22
