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Materials Data on AuClO2 by Materials Project

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Mendeley Data2024-01-31 更新2024-06-29 收录
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https://www.osti.gov/servlets/purl/1317177/
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AuO2Cl crystallizes in the orthorhombic C222_1 space group. The structure is two-dimensional and consists of two AuO2Cl sheets oriented in the (0, 1, 0) direction. Au5+ is bonded in a rectangular see-saw-like geometry to two equivalent O2- and two equivalent Cl1- atoms. Both Au–O bond lengths are 2.09 Å. Both Au–Cl bond lengths are 2.44 Å. O2- is bonded in a distorted bent 120 degrees geometry to one Au5+ and one O2- atom. The O–O bond length is 1.32 Å. Cl1- is bonded in a distorted water-like geometry to two equivalent Au5+ atoms.
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2024-01-31
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