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2,3-Migration in Rh(II)-Catalyzed Reactions of β-Trifluoroacetamido α-Diazocarbonyl Compounds

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NIAID Data Ecosystem2026-03-06 收录
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The hydroxy group was directly converted into the trifluoroacetamido group by reacting β-hydroxy-α-diazo carbonyl compounds with trifluoroacetimidoyl chloride in the presence of DBU. Rh(II)-catalyzed reactions of these diazo compounds gave 2,3-migration products in high yields.

创建时间:
2016-03-01
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