Synthetic Entry into 1‑Phosphono-3-azabicyclo[3.1.0]hexanes
收藏Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthetic_Entry_into_1_Phosphono_3_azabicyclo_3_1_0_hexanes/2379628
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3-Azabicyclo[3.1.0]hex-2-en-1-yl phosphonates were prepared in a five-step reaction route from β-ketophosphonates. The key steps in this sequence are an atom-transfer radical cyclization and an unforeseen lithium–halogen exchange with n-BuLi. The cyclization reaction proceeds with excellent diastereoselectivity. The resulting cyclic imines were reduced, and 3-azabicyclo[3.1.0]hexan-1-yl phosphonates were obtained.
创建时间：
2016-02-18
