Synthesis, Characterization, and Tautomerism of Four Novel Copper(I) Complexes from 3-Hydroxy-3-(<i>p</i>-R-phenyl)-2-propenedithioic Acids
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The paper describes the synthesis and structural characterization of four novel copper(I) complexes [CuL(PPh3)2] (L = 3-hydroxy-3-(p-R-phenyl)-2-propenedithioate). In addition, a tautomeric equilibrium in solution was found and Hammett correlations with 13C NMR parameters were studied. The structure of one complex was fully established by X-ray diffraction analysis.
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2004-12-27
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