Side-On Coordination of Nitrous Oxide to a Mononuclear Cobalt Center
收藏NIAID Data Ecosystem2026-03-11 收录
下载链接：
https://figshare.com/articles/dataset/Side-On_Coordination_of_Nitrous_Oxide_to_a_Mononuclear_Cobalt_Center/9807614
下载链接
链接失效反馈官方服务：
资源简介：
Despite
its utility as an oxygen-atom transfer reagent for transition
metals, nitrous oxide (N2O) is a notoriously poor ligand,
and its coordination chemistry has been limited to a few terminal,
end-on κ1-N complexes. Here, the
synthesis of a mononuclear cobalt complex possessing a side-on-bound
N2O molecule is reported. Structural characterization,
IR spectroscopy, and DFT calculations support an η2-N,N binding mode for binding of N2O
to the cobalt center.
创建时间：
2019-09-06
