Homo- and Heterobismetal Complexes of 5-Hydroxy-10,15,25,30-tetrakis(pentafluorophenyl)-Substituted [26]Hexaphyrin(1.1.1.1.1.1)
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Metalation of meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1) (4) with CuII and ZnII ions afforded homodinuclear complexes 6 and 7, respectively. A demetalation−remetalation protocol provided monozinc(II) complex 9 selectively, from which copper(II)−zinc(II) heterodinuclear complex 10 was prepared effectively.
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2016-02-26
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