Facile Synthesis of Complicated 9,9-Diarylfluorenes Based on BF<sub>3</sub>·Et<sub>2</sub>O-Mediated Friedel−Crafts Reaction
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BF3·OEt2-mediated Friedel−Crafts reaction of 9-phenyl-fluoren-9-ol with electron-rich aromatic substrates to prepare a new family of complicated 9,9-diarylfluorenes is described. The 9,9-diarylfluorenes tethered with various functional substituents, e.g., bulky spiro units, hole-transporting moieties, and fluorescent dyes, will be promising building blocks for the construction of optoelectronic materials.
创建时间:
2006-08-17



