Organocatalytic Synthesis of Multiple Substituted Bicyclo[4.4.0]Decalin System
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/Organocatalytic_Synthesis_of_Multiple_Substituted_Bicyclo_4_4_0_Decalin_System/2655805
下载链接
链接失效反馈官方服务：
资源简介：
An efficient and unprecedented organocatalytic reaction of γ-nitroketones with α,β-unsaturated aldehydes to give polyfunctionalized [4.4.0] bicyclic skeletons was developed. The diphenylprolinol silyl ether mediated nitro-Michael/Aldol reaction afforded the hexa-substituted decalin carboaldehydes with excellent diastereo- and enantioselectivity (up to >99:1 dr and >99% ee) via a formal [4 + 2] carbocyclization process.
创建时间：
2011-05-06
