Rauhut–Currier Reaction of Nitroalkenes with Vinyl Sulfones
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https://figshare.com/articles/dataset/Rauhut_Currier_Reaction_of_Nitroalkenes_with_Vinyl_Sulfones/2413978
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资源简介:
The Rauhut–Currier reaction
between nitroalkenes and vinyl
sulfones has been successfully carried out for the first time. The
reaction proceeds in the presence of an imidazole/LiCl catalyst system
in dioxane to provide the adducts possessing a synthetically useful
1-bis-sulfonyl-3-nitroalkene moiety in good to excellent yield. A
one-pot transformation of the products to β-sulfonyl-α,β-unsaturated
ketoximes has also been demonstrated.
创建时间:
2013-05-17



