Synthesis and Characterization of Iron Trisphenolate Complexes with Hydrogen-Bonding Cavities
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Iron_Trisphenolate_Complexes_with_Hydrogen_Bonding_Cavities/2314609
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资源简介：
A new
family of C3-symmetric ligands, featuring
phenolate donors and a secondary coordination sphere, have been synthesized.
We report the synthesis and subsequent coordination chemistry of these
new tripodal N-anchored tris(phenolate) chelates, [tris(5-tert-butyl-3-N-carboxamide-2-hydroxybenzyl)amines]
(H3RSalAmi), to iron(II), iron(III), and zinc(II).
These electron-rich complexes have intramolecular hydrogen bonds,
and therefore the potential to stabilize biologically relevant substrates
in small-molecule activation chemistry.
创建时间：
2014-03-17
