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Synthesis and First Molecular Structure of a Bis-2-spiro-1-boraadamantane Derivative

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https://figshare.com/articles/dataset/Synthesis_and_First_Molecular_Structure_of_a_Bis_2_spiro_1_boraadamantane_Derivative/3351064
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A new method for synthesizing the 2-spiro-boraadamantane pyridine complex (2) from 1-ethynylcyclohexylmethyl ether has been developed. The chemistry has been applied to the synthesis of bis-2-spiro-1-boraadamantane·pyridine (1) from trans-1,4-diethynyl-1,4-dimethoxycyclohexane (8). This bis-Lewis acid serves as a self-assembling molecular building block with difunctional Lewis bases.
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2016-05-07
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