Nonconventional Behavior of NCN-Chelated Organoantimony(III) Sulfide and Isolation of Cyclic Organoantimony(III) Bis(pentasulfide)
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https://figshare.com/articles/dataset/Nonconventional_Behavior_of_NCN_Chelated_Organoantimony_III_Sulfide_and_Isolation_of_Cyclic_Organoantimony_III_Bis_pentasulfide_/2812945
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资源简介：
Organoantimony(III) sulfide (1) containing the NCN chelating ligand L [L = 2,6-(CH2NMe2)2C6H3] displays unusual dual behavior, being dimeric (LSbS)2, with the central Sb2S2 core, in the solid state but monomeric in solution. Sulfide 1 reacts with elemental S to give the unprecedented cyclic bis(pentasulfide) LSb(μ-S5)2SbL (2) with the central 12-membered ring Sb2S10.
创建时间：
2016-02-25
