Unprecedented Bending and Rearrangement of f-Element Sandwich Complexes Induced by Superbulky Cyclooctatetraenide Ligands
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https://figshare.com/articles/dataset/Unprecedented_Bending_and_Rearrangement_of_f_Element_Sandwich_Complexes_Induced_by_Superbulky_Cyclooctatetraenide_Ligands/2693281
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资源简介:
The use of the superbulky cyclooctatetraenide dianion ligand [C8H6(SiPh3)2]2− (= COTBIG) in organo-f-element chemistry leads to unprecedented effects such as the formation of a significantly bent anionic CeIII sandwich complex, a novel cerocene formed by sterically induced SiPh3 group migration, as well as the first example of a bent uranocene.
创建时间:
2011-02-09



