‘Stereochemically’ active / non-active lone pair in HP lead-containing phases
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https://doi.esrf.fr/10.15151/ESRF-ES-644970347
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The study of Pb-containing compounds under high-pressure can help to understand the process of ‘activation’ of lone pair. In order to our previous studies of unusual behavior of MB2Si2O8 (M = Ca,Sr,Ba) [Pakhomova et al., 2017; Gorelova et al., 2020] and CaBe2P2O8 [Pakhomova et al., 2019] we suppose to study isostructural compounds with Pb-replacement cations. The knowledge about such a crystal structures has major relevance for physical properties of the materials.
创建时间：
2025-01-01
