Osmium-Mediated Direct C–H Bond Activation at the 8‑Position of Quinolines
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https://figshare.com/articles/dataset/Osmium_Mediated_Direct_C_H_Bond_Activation_at_the_8_Position_of_Quinolines/3382786
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资源简介：
Metal-mediated direct
C–H bond activation at the 8-position
of quinolines, which is the essential step for the functionalization
of this bond, is promoted by the hexahydride OsH6(PiPr3)2. This complex activates quinoline
and 2-, 3-, 6-, and 7-methylquinoline to afford the classical trihydride
derivatives OsH3{κ2-C8,N-(quinolinyl)}(PiPr3)2 and OsH3{κ2-C8,N-(quinolinyl-n-Me)}(PiPr3)2 (n = 2, 3, 6, 7), containing a four-membered heterometalla ring.
创建时间：
2016-06-07
