Interplay of protection and damage through intermolecular processes in the decay of electronic core holes in microsolvated organic molecules

Data set pertaining to the manuscript "Interplay of protection and damage through intermolecular processes in the decay of electronic core holes in microsolvated organic molecules", under consideration for publication at PCCP (Physical Chemistry Chemical Physics).

The manuscript describes results on the intermolecular energy- and charge-transfer processes from core-ionized water in pyrimidine-water clusters.

Dataset: EII_coinc.txt

Electron-ion-ion coincidences

Photon energy: 620 eV

Total acquisition time: 43:40 min

Detection window: 1600 ns

Pressure main chamber: 3.28 * 10-6 mbar

Temperature nozzle/reservoir: 80 °C

Target: Pyrimidine-water-vapor (from 94% water and 6% pyrimidine in solution)

First columns:             time of flight of electron in ns

Second columns:        time of flight of first detected ion in ns

Third columns:            time of flight of second detected ion in ns

Delimiter:  , 

Recorded at Petra III, P04-Beamline, in 40-Bunch mode with a time spacing between two exciting pluses of 192ns.

Experiment: Magnetic-bottle time of flight electron spectrometer combined with ion time of flight spectrometer, a cluster source and synchrotron radiation

Detector/Spectrometer voltages:

Ion MCP detector signal: + 430 V

Ion MCP detector events: -2700V

Ion drift tube: -2700 V

Extractor: -1300 V

Pusher: -600 V

Retardation 1: -1150 V

Retardation 2: -600 V

Retardation 3: -1100 V

Retardation 4: -1100 V

Electron drift tube: -1050 V

Electron MCP detector events: -1000 V

Electron MCP detector signal: +1750 V

Coil current: 1.4 A

Contact:     Dana Bloß    ([e-mail])                                                                                                                                                                                                                    Andreas Hans    ([e-mail])