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A Concise Total Synthesis of (±)- and (−)-Okilactomycin D

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Concise_Total_Synthesis_of_and_Okilactomycin_D/2553784
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The spirotetronate okilactomycin D (7) has been efficiently synthesized by a route featuring a substrate-controlled, diastereoselective (8:1) intramolecular Diels–Alder (IMDA) reaction of 11. The assigned absolute configuration of (−)-7 was confirmed.
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2016-02-22
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