Zinc-Catalyzed Hydrosilylation and Hydroboration of N‑Heterocycles
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https://figshare.com/articles/dataset/Zinc-Catalyzed_Hydrosilylation_and_Hydroboration_of_N_Heterocycles/5596729
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资源简介：
The zinc hydride
NacNacZnH (2) (NacNac = [Ar′NC(Me)CHC(Me)NAr′]−, Ar′ = 2,6-Me2C6H3) catalyzes regioselective hydrosilylation and hydroboration
of pyridines, including the hydroboration of phenanthroline. Mechanistic studies of hydrosilylation,
including labeling, kinetic analysis, and density functional theory
calculations, suggest the possibility of a reaction pathway based
on hydride transfer from an out-of-sphere activated silane.
创建时间：
2017-11-13
