Amine-Assisted C−Cl Bond Activation of Aryl Chlorides by a (Phebox)Rh-Chloro Complex
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
Oxidative addition of chlorobenzene and p-chlorotoluene by (Phebox)RhCl2(H2O) (1) in the presence of diisopropylamine was examined and was shown to produce the corresponding aryl complexes (Phebox)RhCl(Ar)(H2O) in high yields via C−Cl bond cleavage. Reaction of 1 with chloropyridine in the presence of diisopropylamine provided a pyridinium rhodate complex.
创建时间：
2016-02-27
