Cupric Superoxo-Mediated Intermolecular C−H Activation Chemistry
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The new cupric superoxo complex [LCuII(O2•−)]+, which possesses particularly strong O−O and Cu−O bonding, is capable of intermolecular C−H activation of the NADH analogue 1-benzyl-1,4-dihydronicotinamide (BNAH). Kinetic studies indicated a first-order dependence on both the Cu complex and BNAH with a deuterium kinetic isotope effect (KIE) of 12.1, similar to that observed for certain copper monooxygenases.
创建时间：
2016-02-23
