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Oligomerization of Phenylacetylene to Coordinated 2,3,6-Triphenylfulvene in Molybdenum Tetracyclone Complexes

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Figshare2016-02-20 更新2026-04-29 收录
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The reaction of [Mo­(CO)2(η-C4Ph4CO)2] with phenylacetylene gave [Mo­(CO)­(η-C4Ph4CO)­(η6-2,3,6-C4H2Ph2CCHPh)], in which [2 + 2 + 1] cyclotrimerization of three alkyne molecules to give a fulvene ligand has occurred.

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2016-02-20
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