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Transition-Metal-Free Addition Reaction for the Synthesis of 3‑(Aminobenzylidene/aminoalkylidene)indolin-2-ones and Its Synthetic Applications

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Figshare2019-09-26 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Transition-Metal-Free_Addition_Reaction_for_the_Synthesis_of_3_Aminobenzylidene_aminoalkylidene_indolin-2-ones_and_Its_Synthetic_Applications/9968177
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资源简介:
A novel and efficient transition-metal-free approach for the exclusive synthesis of Z-3-(aminobenzylidene/aminoalkylidene)­indolin-2-ones in high yield from 2-oxindole and aryl/alkyl nitrile in the presence of LiOtBu and 2,2′-bipyridine system is described. In addition, we disclosed a new approach towards the metal-free fluorination using selectfluor and the CC bond cleavage using CuI and environmentally benign O2.
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2019-09-26
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