Preparation and Aromaticity of Rhenacycloprop-2-ene-containing Polycyclic Compounds
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https://figshare.com/articles/dataset/Preparation_and_Aromaticity_of_Rhenacycloprop-2-ene-containing_Polycyclic_Compounds/24175111
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资源简介：
In this work, we present the synthesis and characterization
of
fused rhenabenzofuran and rhenapyrylium complexes with a metallacycloprop-2-ene
unit from the reactions of ReCl3(PMePh2)3 with alkynylphenols and alkynylacetophenones, respectively.
The aromaticity of these structures is investigated by DFT studies,
showing σ-predominant aromaticity in the three-membered metallacycloprop-2-ene
units.
创建时间：
2023-09-21
