Versatile Route to Arylated Fluoroalkyl Bromide Building Blocks
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https://figshare.com/articles/dataset/Versatile_Route_to_Arylated_Fluoroalkyl_Bromide_Building_Blocks/2080714
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资源简介:
New
difunctionalized and fluoroalkylated silyl reagents have been
prepared that react with silver and copper salts to afford active
catalysts that can be used to synthesize arylated fluoroalkyl bromide
building blocks. It has been shown that the [(phen)Ag(CF2)nBr] intermediates are capable of transferring
both the phenanthroline ligand and the fluoroalkyl bromide chain to
copper iodide, eliminating the need for a preligated copper salt precursor.
The methodology is compatible with various chain lengths of the fluoroalkyl
halide functionality.
创建时间:
2016-02-12



