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Highly Selective Ring Expansion of Bicyclo[3.1.0]hexenes

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NIAID Data Ecosystem2026-03-09 收录
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A Ru-carbene-promoted ring expansion of bicyclo­[3.1.0]­hexenes with terminal alkynes is reported. The reaction delivers seven-membered carbocycles starting from readily available starting materials and was found to be highly regioselective. The resulting seven-membered ring products contain both conjugated diene and cyclopropane substructures that could be selectively reacted in subsequent transformations.

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2016-10-17
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