Chiral Norbornadienes as Efficient Ligands for the Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Fumaric and Maleic Compounds
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https://figshare.com/articles/dataset/Chiral_Norbornadienes_as_Efficient_Ligands_for_the_Rhodium_Catalyzed_Asymmetric_1_4_Addition_of_Arylboronic_Acids_to_Fumaric_and_Maleic_Compounds/3324877
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资源简介:
A rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to fumaric and maleic compounds has been developed. While phosphorus-based chiral ligands fail to induce high stereoselectivity, chiral norbornadiene ligands have proved to be uniquely effective to achieve high
enantioselectivity in these 1,4-addition reactions.
创建时间:
2016-05-06



