Modulation of the Photochromic Property in an Organoboron-Based Diarylethene by a Fluoride Ion
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Organoboron-based diarylethene was successfully synthesized and exhibited photochromic property. Furthermore, its photochromic property can be modulated by a fluoride ion. The absorption maximum of the photostationary state shifted from 655 to 490 nm upon addition of a fluoride ion. The modulation mechanism is attributed to the special Lewis acid−base interaction between a trivalent boron atom and a fluoride ion.
创建时间：
2016-02-29
