A Binuclear MnIII Complex of a Scorpiand-Like Ligand Displaying a Single Unsupported MnIII–O–MnIII Bridge
收藏Figshare2016-02-20 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/A_Binuclear_Mn_sup_III_sup_Complex_of_a_Scorpiand_Like_Ligand_Displaying_a_Single_Unsupported_Mn_sup_III_sup_O_Mn_sup_III_sup_Bridge/2472457
下载链接
链接失效反馈官方服务：
资源简介：
The crystal structure of a binuclear MnIII complex of a scorpiand-like ligand (L) displays an unsupported single oxo bridging ligand with a MnIII–O–MnIII angle of 174.7°. Magnetic susceptibility measurements indicate strong antiferromagnetic coupling between the two metal centers. DFT calculations have been carried out to understand the magnetic behavior and to analyze the nature of the observed Jahn–Teller distortion. Paramagnetic 1H NMR has been applied to rationalize the formation and magnetic features of the complexes formed in solution.
创建时间：
2016-02-20
