Tetralithiated Tetraazaperopyrene as a Key Intermediate for the Synthesis of Functionalized Derivatives
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https://figshare.com/articles/dataset/Tetralithiated_Tetraazaperopyrene_as_a_Key_Intermediate_for_the_Synthesis_of_Functionalized_Derivatives/2171071
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资源简介:
A new
synthetic approach to core-functionalized tetraazaperopyrenes
(TAPP) is reported. In-situ reaction of 4-fold lithiated TAPP with
electrophiles results in the formation of various unprecedented TAPP
derivatives, which are highly emissive fluorophores, show promising
photophysical and electrochemical properties and act as valuable starting
materials. Thus, lithiation of the TAPP core opens up a facile way
for developing new organic materials.
创建时间:
2016-02-13



