Platinum-Catalyzed Chemoselectively Hydrative Dimerization of 2-Alkynyl-1-acetylbenzenes for One-Pot Facile Synthesis of Chrysene Derivatives
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https://figshare.com/articles/dataset/Platinum_Catalyzed_Chemoselectively_Hydrative_Dimerization_of_2_Alkynyl_1_acetylbenzenes_for_One_Pot_Facile_Synthesis_of_Chrysene_Derivatives/2972884
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资源简介：
We report one-pot syntheses of chrysene compounds via PtCl2-catalyzed hydrative dimerization of readily
available 2-alkynyl-1-acetylbenzenes. This new tandem catalysis comprises an initial selective hydration
of the alkyne, followed by chemoselective dimerization of diketone intermediates. The mechanism of
this cyclization has been elucidated by 13C labeling experiments as well as isolation of reaction
intermediates.
创建时间：
2016-06-03
