Synthesis, Structure, and Bonding of a Polyhedral Al<sub>2</sub>Co<sub>2</sub> Cluster
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Bis(μ-(pentamethylcyclopentadienyl)aluminio)hexacarbonyldicobalt, (μ-Cp*Al)2Co2(CO)6, is formed in the reaction between AlCp* (Cp* = C5Me5) and Co2(CO)8 in toluene. The bonding description as a polyhedral Al2Co2 cluster in which AlCp* has completely lost its originally carbene-like character is based on X-ray data as well as on DFT calculations.
创建时间:
2016-08-27



