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Helical Chiral 2,2′-Bipyridine N- Monoxides as Catalysts in the Enantioselective Propargylation of Aldehydes with Allenyltrichlorosilane

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Helical_Chiral_2_2_Bipyridine_i_N_i_Monoxides_as_Catalysts_in_the_Enantioselective_Propargylation_of_Aldehydes_with_Allenyltrichlorosilane/2672890
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A highly enantioselective synthesis of homopropargylic alcohols is achieved by using the new helical chiral 2,2′-bipyridine N-monoxide catalyst and allenyltrichlorosilane. This method can be further extended to the enantio- and regioselective propargylation of N-acylhydrazones.
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2016-02-23
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