Metal-Only Lewis Pairs Based on Zerovalent Osmium
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https://figshare.com/articles/dataset/Metal-Only_Lewis_Pairs_Based_on_Zerovalent_Osmium/3495923
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A series of zerovalent osmium carbonyl complexes have been treated with Lewis acids GaCl3 and Ag+ to gauge their Lewis basicity. Additionally, comparisons are made between these osmium compounds and analogous iron and ruthenium carbonyl complexes by transfer reactions. This allows direct comparison of the group 8 carbonyl complexes to each other and the establishment of a trend of their Lewis basicity.
创建时间：
2016-08-02
