Bis-Tris Propane as a New Polydentate Linker in the Synthesis of Iron(III) and Manganese(II/III) Complexes
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We describe the synthesis, structure, and magnetic properties of two new complexes, one decanuclear iron(III) cluster and one hexanuclear mixed-valence manganese(II/III) cluster, where the previously unexplored polydentate ligand Bis-tris propane {(CH2OH)3CNH(CH2)3NHC(CH2OH)3} is used to link small cluster fragments into high-nuclearity complexes.
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2016-02-27
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