Direct Observation of a {Re6(μ3-S)8} Core-to-Ligand Charge-Transfer Excited State in an Octahedral Hexarhenium Complex
收藏Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Direct_Observation_of_a_Re_sub_6_sub_sub_3_sub_S_sub_8_sub_Core_to_Ligand_Charge_Transfer_Excited_State_in_an_Octahedral_Hexarhenium_Complex/2601160
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A new complex, [Re6S8Cl5ppy]3– (ppy = 4-phenylpyridine), was synthesized and characterized. The complex showed red emission at 296 K in both the crystalline phase and CH3CN. The transient absorption spectrum of [Re6S8Cl5ppy]3– revealed that the emissive excited state involved the {Re6(μ3-S)8} core-to-ligand charge-transfer character.
创建时间：
2016-02-22
