Synthesis and Crystal Structure of Two Interpenetrated Open Frameworks with Different Structural Motifs
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Synthesis_and_Crystal_Structure_of_Two_Interpenetrated_Open_Frameworks_with_Different_Structural_Motifs/3055444
下载链接
链接失效反馈官方服务：
资源简介：
Two three-dimensional interpenetrating coordination polymers, [Co(C8H4O4)(C12H10N2)]n, 1, and [Zn3(C14H8O4)3
(C12H10N2)2]n, 2, have been prepared hydrothermally by the assembly of cobalt(II), 1,2-bis(4-pyridyl)ethene (C12H10N2) with terephthalic
acid (C8H4O4), and zinc(II), 1,2-bis(4-pyridyl)ethene with biphenyl-4,4‘-dicarboxylic acid (C14H8O4), respectively. Single-crystal
X-ray diffraction analyses reveal that 1 and 2 have similar 2-fold interpenetration. Because of the influence of metal ions, the
O,O‘-donor ligands adopt similar coordination modes but form different kinds of individual motifs, which finally aggregate to
generate different supramolecular architectures. The structures of the two three-dimensional interpenetrating open frameworks have
been characterized and studied.
创建时间：
2016-02-29
