1,1‘-Oligosilylferrocene Compounds
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https://figshare.com/articles/dataset/1_1_-Oligosilylferrocene_Compounds/12072210
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资源简介:
1,1‘-Bis[tris(trimethylsilyl)silyl]ferrocene (1) was prepared by reaction of 2 equiv of lithiated tris(trimethylsilyl)silylcyclopentadiene with FeBr2. Treatment of 1 with 2 equiv of potassium tert-butoxide
gave 1,1‘-bis[bis(trimethylsilyl)potassiosilyl]ferrocene (2). Reactions of 2 with several dielectrophiles
led to the formation of a number of novel 1,1‘-polysilyl ansa-ferrocenes with different heteroelements in
the bridge.
创建时间:
2007-03-26



