Copper Complex of an Iminodioxabicyclo[3.3.1]nonane Pendant Ligand: The First Example of Iminodioxocin Bridgehead Nitrogen Coordination
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https://figshare.com/articles/dataset/Copper_Complex_of_an_Iminodioxabicyclo_3_3_1_nonane_Pendant_Ligand_The_First_Example_of_Iminodioxocin_Bridgehead_Nitrogen_Coordination/4009224
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资源简介：
The pentadentate N4O amine−imine−naphthol ligand (HLD) containing rigid 8,16-imino-8H,16H-dinaphtho[2,1-b:2,1-f][1,5]dioxocin
is formed preferentially, under visible light irradiation conditions,
instead of the product H3L, expected from imidazolidine ring
formation. A strained chelate bite enforces the first bridgehead
nitrogen coordination to a copper(II) ion from the bicyclic iminodioxocin part of the ligand as shown by X-ray crystallography.
创建时间：
2016-10-12
