Metal-Assisted Regio- and Stereospecific Insertion of Alkynes into a C−H Bond, Leading to Functionalized Diphosphane Ligands
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Metal_Assisted_Regio_and_Stereospecific_Insertion_of_Alkynes_into_a_C_H_Bond_Leading_to_Functionalized_Diphosphane_Ligands/3353017
下载链接
链接失效反馈官方服务：
资源简介：
Reaction of the complex fac-[Mn(CNtBu)(CO)3{(PPh2)2C−H}] (1) with dimethyl acetylenedicarboxylate and methyl propiolate affords the compounds
fac-[Mn(CNtBu)(CO)3{(PPh2)2CC(R)C(R‘)−H}] (2a, R
= R‘ = CO2Me; 2b, R = H, R‘ = CO2Me), as a result of
regio- and stereospecific insertion of the alkynes into the
C−H bond of the diphosphanylmethanide ligand, allowing highly selective metal-assisted synthesis of new
functionalized diphosphane derivatives.
创建时间：
2004-01-19
