Table 1 1 H in Antifeedant, cytotoxic, and anti-inflammatory neo-clerodane diterpenoids in the peltate glandular trichomes and fresh leaves of Ajuga forrestii

Table 1 1 H NMR spectroscopic data of compounds 8a/b and 9a/b (δ in ppm, J in Hz). H no.8a a8b a9a a9b a11.62 m1.62 m1.63 m1.63 m1.60 m1.60 m21.98 m1.98 m1.99 m1.99 m1.54 m1.54 m1.54 m1.54 m32.12 m2.12 m2.11 m2.11 m1.13 brd1.13 brd1.12 dt (9.3,1.12 dt (9.3,(13.2)(13.2)3.2)3.2)63.69 m3.69 m3.67 dt (11.4,3.67 dt (11.4,3.7)3.7)71.56 m1.56 m1.56 m1.56 m1.48 m1.48 m1.48 m1.48 m81.66 m1.66 m1.66 m1.66 m101.51 m1.51 m1.51 m1.51 m111.58 m1.58 m1.45 m1.45 m1.44 m1.44 m122.04 m2.04 m2.05 m2.05 m1.91 m1.91 m1.91 m1.91 m145.68 s5.68 s5.67 brs5.67 brs162.15 s2.15 s2.14 s2.14 s173.34 m3.34 m3.33 dd (5.6,3.33 dd (5.6,3.4)3.4)2.52 m2.52 m2.51 d (3.4)2.51 d (3.4)184.70 d (11.8)4.76 d (11.8)4.73 d (12.0)4.69 m4.56 d (11.5)4.53 d (11.5)4.56 d (12.0)4.53 d (12.0)190.74 s0.74 s0.734 s0.736 s200.88 d (6.7)0.88 d (6.7)0.87 d (6.8)0.87 d (6.8)3′6.50 d (0.8)6.49 d (0.8)6.38 s6.38 s5.93 d (0.8)5.94 d (0.8)5.92 t (1.4)5.91 t (1.4)4′4.93 q (3.5)4.93 q (3.5)4.69 m4.69 m5′1.29 d (6.6)1.29 d (6.6)1.29 d (1.6)1.30 d (1.6)15-3.65 s3.65 s3.65 s3.65 sOCH3 1 H NMR spectra of compound 8a / 8b were recorded in CD OD at 600 MHz, and 3 1 H NMR spectra of compound 9a / 9b were recorded in CD OD at 800 MHz. 3 a Data set interchangeable between “ a ” and “ b ”.