Unusual Oxidation of an N-Heterocycle Ligand in a Metal−Organic Framework
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https://figshare.com/articles/dataset/Unusual_Oxidation_of_an_N_Heterocycle_Ligand_in_a_Metal_Organic_Framework/2997751
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资源简介：
An in situ ligand reaction from the pyridine cycle to −COO- in the
copper−organic framework is achieved under hydrothermal conditions. Compound [Cu2(bpa)4] [1; bpa = 5-(4-bromophenyl)picolinic
acid] exhibits a one-dimensional chain architecture based on weak
Cu−O interactions. The mechanism of ligand transformation is
discussed.
创建时间：
2016-06-03
