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Metal-Stabilized Phenoxonium Cation

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Metal_Stabilized_Phenoxonium_Cation/3355588
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An unprecedented metal-stabilized phenoxonium cation was prepared by a process involving dearomatization of a phenoxy complex. The unique η2 CO−metal (iridium) coordination mode leaves the positive charge delocalized within the former aromatic ring. The X-ray structure and conversion into η2 CO-coordinated metal−quinone complex are described.
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2016-05-07
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